Solvothermal synthesis and structure of anhydrous manganese(II) formate, and its topotactic dehydration from manganese(II) formate dihydrate

被引：65

作者：

Viertelhaus, M ^{[1
]}

Henke, H ^{[1
]}

Anson, CE ^{[1
]}

Powell, AK ^{[1
]}

机构：

[1] Univ Karlsruhe, Inst Anorgan Chem, D-76128 Karlsruhe, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2003年 / 12期

关键词：

manganese; formates; solvothermal synthesis; solid-state reactions;

D O I：

10.1002/ejic.200200699

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Recrystallization of manganese(II) formate dihydrate from formic acid under solvothermal conditions results in single crystals of anhydrous manganese(II) formate Mn(O2CH)(2), and the structure of this phase has been determined by Xray diffraction. The same product can be obtained by solid-state dehydration of single crystals of manganese formate dihydrate, giving crystals that, although of poor quality, still allow for a single crystal structure determination. The structural relationship between the hydrated and anhydrous phases and the nature of the transformation have been determined. Given the nature of the rearrangement involved in the solid-state reaction, it is remarkable that a crystalline product is obtained. Magnetic measurements of the anhydrous manganese(II) formate show it to be a three-dimensional antiferromagnet. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).

引用

页码：2283 / 2289

页数：7

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