Recyclable ionic liquid-bridged chiral dimeric salen Mn(III) complexes for oxidative kinetic resolution of racemic secondary alcohols

被引：18

作者：

Li, Chengyong ^{[1
]}

Zhao, Jiangfeng ^{[1
]}

Tan, Rong ^{[1
]}

Peng, Zhigang ^{[1
]}

Luo, Rongchang ^{[1
]}

Peng, Ming ^{[1
]}

Yin, Donghong ^{[1
,2
]}

机构：

[1] Hunan Normal Univ, Inst Fine Catalysis & Synth, Changsha 410081, Hunan, Peoples R China

[2] China Tobacco Hunan Ind Corp, R&D Ctr, Changsha 410014, Hunan, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2011年 / 15卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Chiral dimeric salen Mn(III) complexes; Ionic liquids (ILs); Catalysis; Secondary alcohols; Oxidative kinetic resolution; MOLECULAR-OXYGEN; CATALYSTS; EPOXIDATION; MECHANISM; SILICA;

D O I：

10.1016/j.catcom.2011.08.009

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Novel chiral dimeric salen Mn(III) complexes bridged with N,N-dialkylimidazolium ionic liquids (ILs) at the C-5 position of the salicylaldehyde moieties were designed and synthesized. The Its-bridged complexes presented excellent enantioselectivity and catalytic activity in the oxidative kinetic resolution of a-methyl benzyl alcohol, using diacetoxyiodobenzene as oxidant. The complexes combined the high catalytic efficiency of the active centers and the special solubility of the ILs, thus exhibiting notable efficacy of oxidative kinetic resolution and facile recovery from the reaction system by changing the solvent. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：27 / 31

页数：5

共 50 条

[21] Oxidative kinetic resolution of racemic secondary alcohols in water with chiral PNNP/Ir catalyst
Zhang, Juanni
Yang, Xiangren
Zhou, Han
Li, Yanyun
Dong, Zhenrong
Gao, Jingxing
GREEN CHEMISTRY, 2012, 14 (05) : 1289 - 1292
[22] Oxidative kinetic resolution of racemic alcohols catalyzed by chiral ferrocenyloxazolinylphosphine-ruthenium complexes
Nishibayashi, Y
Yamauchi, A
Onodera, G
Uemura, S
JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (15): : 5875 - 5880
[23] Chiral-Mn(salen)-complex-catalyzed kinetic resolution of secondary alcohols in water
Sun, W
Wang, HW
Xia, CG
Li, JW
Zhao, PQ
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (09) : 1042 - +
[24] Enantioselective oxidation of racemic secondary alcohols catalyzed by chiral Mn(III)-salen complex with sodium hypochlorite as oxidant
Zhang, Yuecheng
Zhou, Qiao
Ma, Wenchan
Zhao, Jiquan
CATALYSIS COMMUNICATIONS, 2014, 45 : 114 - 117
[25] Kinetic resolution of racemic secondary alcohols catalyzed by chiral diaminodiphosphine-Ir(I) complexes
Li, Yan-Yun
Zhang, Xue-Qin
Dong, Zhen-Rong
Shen, Wei-Yi
Chen, Gui
Gao, Jing-Xing
ORGANIC LETTERS, 2006, 8 (24) : 5565 - 5567
[26] Chiral recyclable dimeric and polymeric Cr(III) salen complexes catalyzed aminolytic kinetic resolution of trans-aromatic epoxides under microwave irradiation
Kureshy, Rukhsana I.
Prathap, K. Jeya
Singh, Surendra
Agrawal, Santosh
Khan, Noor-ul H.
Abdi, Sayed H. R.
Jasra, Raksh V.
CHIRALITY, 2007, 19 (10) : 809 - 815
[27] Mesoporous helical silica immobilizing manganese(III)-salen complex for oxidative kinetic resolution of secondary alcohols
Lin Ren
Le Li
Yu Li
Guangbin Zhang
Benhua Huang
Zulpiya Imam
Aqun Zheng
Yang Sun
Journal of Porous Materials, 2016, 23 : 19 - 33
[28] Mesoporous helical silica immobilizing manganese(III)-salen complex for oxidative kinetic resolution of secondary alcohols
Ren, Lin
Li, Le
Li, Yu
Zhang, Guangbin
Huang, Benhua
Imam, Zulpiya
Zheng, Aqun
Sun, Yang
JOURNAL OF POROUS MATERIALS, 2016, 23 (01) : 19 - 33
[29] Kinetic resolution of racemic allenes by using chiral (salen)manganese(III) complex as a catalyst
Noguchi, Y
Takiyama, H
Katsuki, T
SYNLETT, 1998, (05) : 543 - +
[30] Hydrolytic kinetic resolution of racemic epichlorohydrin catalyzed by chiral rare earth salen complexes
Zhang, M.-J., 2013, Editorial Office of Chinese Rare Earths, No. 36 Huanghe Street, RE Development Zone, Baotou, 014030, China (34)

← 1 2 3 4 5 →