Indirect catalysis, caused by hydrogen spillover through the gas phase. Activation by hydrogen oxygen reaction

被引：3
|
作者：
Baumgarten, E [1 ]
Meyer, G [1 ]
机构：
[1] Univ Dusseldorf, Abt Angew Phys Chem, Inst Phys Chem & Elektrochem, D-4000 Dusseldorf, Germany
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 2000年 / 71卷 / 02期
关键词：
indirect catalysis; spillover through the gas phase; hydrogen spillover;
D O I：
10.1023/A:1010339512972
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Earlier investigations revealed that glass surfaces may get catalytic properties by hydrogen spillover. Occasional activations by oxyhydrogen reaction, observed there, were executed systematically now and revealed high and stable degrees of activity of glass activated in this way. The activation energies for the hydrogenation of cyclohexene on the glass 'catalyst' are 18.1 kJ mol-1 (T > 367 K) 33.6 kJ mol-1 (T < 367 K)
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页码：335 / 341
页数：7
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