3-Amino-1-(4-fluorophenyl)-3a,3b,6,7-tetrahydrobenz[4,5]indene-2-carbonitrile

被引:0
|
作者
Shi, DQ [1 ]
Rong, L
Wang, JX
Wanga, XS
Hu, HW
机构
[1] Xuzhou Normal Univ, Dept Chem, Xuzhou 221116, Peoples R China
[2] Nanjing Univ, Dept Chem, Nanjing 210093, Peoples R China
关键词
D O I
10.1107/S1600536803020798
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, C20H17FN2, has been synthesized by the reductive cyclization induced by a low-valent titanium reagent. The cyclopentene ring adopts an envelope conformation, while the partially saturated six-membered ring adopts a distorted half-chair conformation. Intermolecular N-H...N hydrogen bonds between the amino and cyano groups result in the formation of a dimer structure.
引用
收藏
页码:O1562 / O1563
页数:2
相关论文
共 50 条
  • [41] 5-Chloro-2-(4-fluorophenyl)-3-phenylsulfinyl-1-benzofuran
    Choi, Hong Dae
    Seo, Pil Ja
    Son, Byeng Wha
    Lee, Uk
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O498 - U1798
  • [42] 5-Cyclohexyl-2-(4-fluorophenyl)-3-methylsulfinyl-1-benzofuran
    Choi, Hong Dae
    Seo, Pil Ja
    Son, Byeng Wha
    Lee, Uk
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O470 - U1539
  • [43] 5-Cyclopentyl-2-(4-fluorophenyl)-3isopropylsulfonyl-1-benzofuran
    Choi, Hong Dae
    Seo, Pil Ja
    Lee, Uk
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O3336 - +
  • [44] 2-(4-Fluorophenyl)-3-methylsulfanyl-5phenyl-1-benzofuran
    Choi, Hong Dae
    Seo, Pil Ja
    Son, Byeng Wha
    Lee, Uk
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O2766 - U919
  • [45] 2-(4-Fluorophenyl)-1-(3-methoxyphenyl)-4,5-dimethyl-1H-imidazole
    Begum, S. Rizwana
    Hema, R.
    Srinivasan, N.
    Anitha, A. G.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : O14 - +
  • [46] 3-(4-Fluorophenyl)-1-(1-(4-fluorophenyl)-3,3,3-trifluoroprop-1-en-1-yl)-5-fluoro-1H-pyrazole
    Paveliev, Stanislav A.
    Ustyuzhanin, Alexander O.
    Krylov, Igor B.
    Terent'ev, Alexander O.
    MOLBANK, 2023, 2023 (02)
  • [47] 5-Cyclohexyl-2-(4-fluorophenyl)-3-isopropylsulfonyl-1-benzofuran
    Choi, Hong Dae
    Seo, Pil Ja
    Son, Byeng Wha
    Lee, Uk
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O1001 - U1622
  • [48] 5-Cyclopentyl-2-(4-fluorophenyl)-3-methylsulfinyl-1-benzofuran
    Seo, Pil Ja
    Choi, Hong Dae
    Son, Byeng Wha
    Lee, Uk
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O2591 - U2014
  • [49] 5-Bromo-2-(4-fluorophenyl)-3-phenylsulfinyl-1-benzofuran
    Seo, Pil Ja
    Choi, Hong Dae
    Son, Byeng Wha
    Lee, Uk
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O2346 - U363
  • [50] 6-Amino-5-(1-amino-2,2-dicyanovinyl)-3,3a,4,5-tetrahydro-2H-indene-4-spiro-1′-cyclopentane-3a,7-dicarbonitrilethiophene-2-carbaldehyde(1/0.5)
    Asiri, Abdullah M.
    Ng, Seik Weng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O2484 - U1700