Efficient synthesis of β-hydroxy sulfides by microwave-promoted ring opening in (+)-3-carene trans-epoxide with sodium thiolates

被引：5

作者：

Agafontsev, Alexander M. ^{[1
]}

Gorshkov, Nikolay B. ^{[1
]}

Tkachev, Alexey V. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia

[2] Novosibirsk State Univ, Dept Nat Sci, Novosibirsk 630090, Russia

来源：

MENDELEEV COMMUNICATIONS | 2011年 / 21卷 / 04期

基金：

俄罗斯基础研究基金会;

关键词：

3-CARENE OXIDES; SULFOXIDES; THIOLYSIS;

D O I：

10.1016/j.mencom.2011.07.006

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of (+)-3-carene trans-epoxide with sodium thiolates in methanolic solution in a microwave oven at 140 degrees C for 35-40 min affords corresponding (1S,3S,4S,6R)-4-sulfanylcaran-3-ols in 75-95% yields.

引用

页码：192 / 193

页数：2

共 22 条

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