Dimerization of a Metal Complex through Thermally Induced Single-Crystal-to-Single-Crystal Transformation or Mechanochemical Reaction

被引：90
|
作者：
Sun, Jie [1 ,2 ]
Dai, Fangna [1 ]
Yuan, Wenbing [3 ]
Bi, Wenhua [4 ]
Zhao, Xiaoliang [1 ]
Sun, Wenming [1 ]
Sun, Daofeng [1 ]
机构：
[1] Shandong Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Colloid & Interface Chem, Jinan 250100, Shandong, Peoples R China
[2] Ludong Univ, Sch Life Sci, Yantai 264025, Shandong, Peoples R China
[3] Hainan Univ, Sch Mat & Chem Engn, Haikou 570228, Hainan, Peoples R China
[4] Liaocheng Univ, Dept Chem, Liaocheng 252059, Shandong, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 31期
关键词：
dimerization; coordination modes; copper; mechanochemical reactions; SOLID-STATE POLYMERIZATION; COORDINATION POLYMER; ORGANIC FRAMEWORKS; PHOTODIMERIZATION; TOPOCHEMISTRY; NETWORK;
D O I：
10.1002/anie.201101277
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Come together: Monomers of copper carboxylate complex 1 (see picture, Cu blue-green, N blue, O red, S yellow, C gray) can dimerize to 2 when previously H-bonded carboxylate groups coordinate to copper. This dimerization can be induced by thermal single-crystal-to-single-crystal transformation or by mechanochemical reaction. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：7061 / 7064
页数：4
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