Dimerization of a Metal Complex through Thermally Induced Single-Crystal-to-Single-Crystal Transformation or Mechanochemical Reaction

被引：90

作者：

Sun, Jie ^{[1
,2
]}

Dai, Fangna ^{[1
]}

Yuan, Wenbing ^{[3
]}

Bi, Wenhua ^{[4
]}

Zhao, Xiaoliang ^{[1
]}

Sun, Wenming ^{[1
]}

Sun, Daofeng ^{[1
]}

机构：

[1] Shandong Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Colloid & Interface Chem, Jinan 250100, Shandong, Peoples R China

[2] Ludong Univ, Sch Life Sci, Yantai 264025, Shandong, Peoples R China

[3] Hainan Univ, Sch Mat & Chem Engn, Haikou 570228, Hainan, Peoples R China

[4] Liaocheng Univ, Dept Chem, Liaocheng 252059, Shandong, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 31期

关键词：

dimerization; coordination modes; copper; mechanochemical reactions; SOLID-STATE POLYMERIZATION; COORDINATION POLYMER; ORGANIC FRAMEWORKS; PHOTODIMERIZATION; TOPOCHEMISTRY; NETWORK;

D O I：

10.1002/anie.201101277

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Come together: Monomers of copper carboxylate complex 1 (see picture, Cu blue-green, N blue, O red, S yellow, C gray) can dimerize to 2 when previously H-bonded carboxylate groups coordinate to copper. This dimerization can be induced by thermal single-crystal-to-single-crystal transformation or by mechanochemical reaction. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7061 / 7064

页数：4

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