Reactions of 1,2,4,5-tetrafluoro-3,6-bis(vinylsulfonyl)benzene with nucleophilic reagents containing a mercapto group

被引:3
|
作者
Amosova, SV [1 ]
Gavrilova, GM [1 ]
Gostevskaya, VI [1 ]
机构
[1] Russian Acad Sci, Irkutsk Inst Chem, Siberian Div, Irkutsk 664033, Russia
关键词
Benzene; Organic Chemistry; Thiol; Title Compound; Thiol Group;
D O I
10.1023/A:1012333719217
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Addition of 2-aminoethanethiol and 2-mercaptocthanol at both vinylsulfonyl groups of 1,2,4,5-tetrafluoro-3,6-bis(vinyisulfonyl)benzene occurs through the thiol group of the reagent and yields the corresponding 3,6-dis[2-(2-aminoethylthio)ethylsulfonyl] and 3,6-bis[2-(2-hydroxyethylthio)ethylsulfonyl] derivatives. The reaction of the title compound with 1,2-ethanedithiol leads to formation of only polymeric addition products.
引用
收藏
页码:93 / 95
页数:3
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