Efficient sensing of nitrite by Fe(bpy)32+ immobilized Nafion modified electrodes

被引:50
|
作者
Azad, Uday Pratap [1 ]
Ganesan, Vellaichamy [1 ]
机构
[1] Banaras Hindu Univ, Fac Sci, Dept Chem, Varanasi 221005, Uttar Pradesh, India
关键词
ELECTROCATALYTIC OXIDATION; HYDROGEN-PEROXIDE; CARBON ELECTRODE; POLYMER-FILMS; COMPLEXES; MEMBRANE; SENSOR; 2,2'-BIPYRIDINE; CATALYSIS; FE(II);
D O I
10.1039/c0cc00852d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Fe(bpy)(3)(2+) (where bpy = 2,2' bipyridyl) immobilized Nafion (Nf) modified glassy carbon electrodes were prepared and they showed excellent electrocatalytic oxidation of nitrite (NO2-) which leads to the sensitive determination of NO2-. Electrostatic repulsion between NO2- and Nf film is greatly decreased when Nf film is fully exchanged with cations.
引用
收藏
页码:6156 / 6158
页数:3
相关论文
共 50 条
  • [21] Electrochemiluminescence of electrodes coated with chitosan encapsulated Ru(bpy)32+/silica gel membrane
    Zhao, Changzhi
    Han, Mei
    Ding, Baojun
    Zhao, Guoliang
    Dalian Ligong Daxue Xuebao/Journal of Dalian University of Technology, 2000, 40 (05): : 550 - 553
  • [22] Determination of malachite green and leucomalachite green based on electrochemiluminescence of Ru(bpy)32+ at graphene oxide modified glassy carbon electrodes
    Shao, Jiantao
    Zhao, Yunmeng
    Liu, Fengyu
    Li, Wei
    Gao, Yulong
    RSC ADVANCES, 2015, 5 (19): : 14547 - 14552
  • [23] An Electrochemiluminescent Detector Based on Multi-Wall-Carbon-Nanotube/Nafion/Ru(bpy)32+ Composite Film Modified Heated-Electrode
    Chen, Yiting
    Jiang, Yingyan
    Lin, Zhenyu
    Sun, Jianjun
    Zhang, Lan
    Chen, Guonan
    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2009, 9 (04) : 2303 - 2309
  • [24] Electrospun Ru(bpy)32+-doped nafion nanofibers for electrochemiluminescence sensing
    Zhou, Cuisong
    Liu, Zhen
    Dai, Jianyuan
    Xiao, Dan
    ANALYST, 2010, 135 (05) : 1004 - 1009
  • [25] Ru(bpy)32+/MWCNTs-Nafion-Silica Nanoparticles Modified Electrochemiluminescent Sensor Based on Molecular Imprinting Technique for Detection of 17β-Estradiol
    Lin Yu-Lin
    Li Xiao-Juan
    Zhang Xin-Ying
    Cao Jie
    Zhang Jian-Hua
    Chen Xiao-Ying
    CHINESE JOURNAL OF ANALYTICAL CHEMISTRY, 2016, 44 (10) : 1547 - 1554
  • [26] An enhanced electrochemiluminescence sensor modified with a Ru(bpy)32+/Yb2O3 nanoparticle/nafion composite for the analysis of methadone samples
    Hosseini, Morteza
    Pur, Mohammad Reza Karimi
    Norouzi, Parviz
    Moghaddam, Mohammad Reza
    Ganjali, Mohammad Reza
    MATERIALS SCIENCE AND ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS, 2017, 76 : 483 - 489
  • [27] Fabrication of a highly efficient solid state electrochemiluminescence sensor using Ru(bpy)32+ incorporated nanoZnO-MWCNTs-Nafion composite film
    Bozorgzadeh, Somayyeh
    Haghighi, Behzad
    Gorton, Lo
    ELECTROCHIMICA ACTA, 2015, 164 : 211 - 217
  • [28] Morphological and voltammetric characterization of different concentrations of spin coated Nafion-Ru(bpy)32+ thin films
    Tuason, B. S. B.
    Tiong-Palisoc, S.
    Tiamzon-Natividad, M.
    1ST INTERNATIONAL CONFERENCE IN APPLIED PHYSICS AND MATERIALS SCIENCE, 2015, 79
  • [29] Electrochemical and electrogenerated chemiluminescence of clay nanoparticles/Ru(bpy)32+ multilayer films on ITO electrodes
    Guo, ZH
    Shen, Y
    Zhao, F
    Wang, MK
    Dong, SJ
    ANALYST, 2004, 129 (07) : 657 - 663
  • [30] Electrochemiluminescence of Ru(bpy)32+ loaded in Nafion Langmuir-Blodgett films: Role of the interfacial ultrathin film
    Moretto, Ligia M.
    Kohls, Thiago
    Badocco, Denis
    Pastore, Paolo
    Sojic, Neso
    Ugo, Paolo
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2010, 640 (1-2) : 35 - 41