共 50 条
Efficient sensing of nitrite by Fe(bpy)32+ immobilized Nafion modified electrodes
被引:50
|作者:
Azad, Uday Pratap
[1
]
Ganesan, Vellaichamy
[1
]
机构:
[1] Banaras Hindu Univ, Fac Sci, Dept Chem, Varanasi 221005, Uttar Pradesh, India
关键词:
ELECTROCATALYTIC OXIDATION;
HYDROGEN-PEROXIDE;
CARBON ELECTRODE;
POLYMER-FILMS;
COMPLEXES;
MEMBRANE;
SENSOR;
2,2'-BIPYRIDINE;
CATALYSIS;
FE(II);
D O I:
10.1039/c0cc00852d
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Fe(bpy)(3)(2+) (where bpy = 2,2' bipyridyl) immobilized Nafion (Nf) modified glassy carbon electrodes were prepared and they showed excellent electrocatalytic oxidation of nitrite (NO2-) which leads to the sensitive determination of NO2-. Electrostatic repulsion between NO2- and Nf film is greatly decreased when Nf film is fully exchanged with cations.
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页码:6156 / 6158
页数:3
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