Rhenium-catalyzed synthesis of indene derivatives via C-H bond activation

被引：21

作者：

Kuninobu, Yoichiro ^{[1
]}

Nishina, Yuta ^{[1
]}

Kawata, Atsushi ^{[1
]}

Shouho, Makoto ^{[1
]}

Takai, Kazuhiko ^{[1
]}

机构：

[1] Okayama Univ, Div Chem & Biochem, Grad Sch Nat Sci & Technol, Okayama 7008530, Japan

来源：

PURE AND APPLIED CHEMISTRY | 2008年 / 80卷 / 05期

关键词：

rhenium; C-H activation; indene; atom-economical;

D O I：

10.1351/pac200880051149

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rhenium complex, [ReBr(CO)(3)(thf)](2)-catalyzed reactions between aromatic imines and either acetylenes or alpha,beta-unsaturated carbonyl compounds gave indene derivatives in good to excellent yields. These reactions proceed via C-H bond activation, insertion of acetylenes or alpha,beta-unsaturated carbonyl compounds, intramolecular nucleophilic cyclization, and reductive elimination. Indene derivatives were also obtained from aromatic ketones and alpha,beta-unsaturated carbonyl compounds in the presence of catalytic amounts of the rhenium complex and p-anisidine. Sequential ruthenium-catalyzed hydroamination of aromatic acetylenes with anilines, and rhenium-catalyzed reactions of the formed aromatic ketimines with alpha,beta-unsaturated carbonyl compounds also provided indene derivatives.

引用

页码：1149 / 1154

页数：6

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