Rhodium(I)-Catalyzed Cycloisomerization of 1,6-Enynes

被引：1
|
作者：
Matsushima, Yuji [1 ]
Phillips, Eric M. [1 ]
Bergman, Robert G. [2 ]
Ellman, Jonathan A. [1 ]
机构：
[1] Yale Univ, Dept Chem, New Haven, CT 06520 USA
[2] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Dept Chem, Berkeley, CA 94720 USA
来源：
SYNLETT | 2015年 / 26卷 / 11期
关键词：
rhodium; homogeneous catalysis; ring closure; isomerization; enones; C-H ACTIVATION; ALPHA; BETA-UNSATURATED KETOXIMES; ENYNE METATHESIS; ALKYNES; PYRIDINES; BOND; TETRAHYDROPYRIDINES; FUNCTIONALIZATION; CYCLIZATION; CATALYSIS;
D O I：
10.1055/s-0034-1380359
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new and unexpected rhodium(I)-catalyzed cycloisomerization of 1,6-enynes is reported. Several different alkyne substitution patterns were evaluated under the reaction conditions, including a deuterated derivative that provides some insight into the reaction mechanism.
引用
收藏
页码：1533 / 1536
页数：4
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