Titanocene-catalyzed double silylation of dienes and aryl alkenes with chlorosilanes

被引：25
|
作者：
Terao, J
Kambe, N [1 ]
Sonoda, N
机构：
[1] Osaka Univ, Fac Engn, Dept Appl Chem, Osaka 5650871, Japan
[2] Kansai Univ, Fac Engn, Dept Appl Chem, Osaka 5648680, Japan
来源：
TETRAHEDRON LETTERS | 1998年 / 39卷 / 52期
基金：
日本学术振兴会;
关键词：
alkenes; dienes; chlorosilanes; double silylation; Grignard reagents; titanium and compounds;
D O I：
10.1016/S0040-4039(98)02227-8
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Double silylation of 1,3-butadienes with chlorosilanes was found to proceed by using titanocene dichloride as the catalyst in the presence of "BuMgCl, giving rise to 1,4-disilylated 2-butenes in good yields. Aryl substituted alkenes also afforded 1,2-disilylated products under similar conditions. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：9697 / 9698
页数：2
相关论文
共 50 条
  • [31] Nickel/Titanocene-Catalyzed Electrophilic Acylation Coupling of Styrene Oxides
    Li, Jincan
    Cao, Chang
    Wu, Haihong
    Dong, Kaiwu
    ORGANIC LETTERS, 2023, 25 (38) : 6959 - 6963
  • [32] Homogeneous, titanocene-catalyzed dehydrocoupling of amine-borane adducts
    Clark, Timothy J.
    Russell, Christopher A.
    Manners, Ian
    Journal of the American Chemical Society, 2006, 128 (30): : 9582 - 9583
  • [33] Titanocene-catalyzed metallation of propargylic acetates in homopropargyl alcohol synthesis
    Meloche, Jennifer L.
    Vednor, Peter T.
    Gianino, Joseph B.
    Oliver, Allen G.
    Ashfeld, Brandon L.
    TETRAHEDRON LETTERS, 2014, 55 (36) : 5025 - 5028
  • [34] DEVELOPMENT OF A TITANOCENE-CATALYZED ENYNE CYCLIZATION ISOCYANIDE INSERTION REACTION
    BERK, SC
    GROSSMAN, RB
    BUCHWALD, SL
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (19) : 8593 - 8601
  • [35] Homogeneous, titanocene-catalyzed dehydrocoupling of amine-borane adducts
    Clark, Timothy J.
    Russell, Christopher A.
    Manners, Ian
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (30) : 9582 - 9583
  • [36] Titanocene-Catalyzed Radical Opening of N-Acylated Aziridines
    Zhang, Yong-Qiang
    Vogelsang, Elisabeth
    Qu, Zheng-Wang
    Grimme, Stefan
    Gansaeuer, Andreas
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (41) : 12654 - 12657
  • [37] A titanocene-catalyzed intramolecular ene reaction: Cycloisomerization of enynes and dienynes
    Sturla, SJ
    Kablaoui, NM
    Buchwald, SL
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (09) : 1976 - 1977
  • [38] Zirconocene-catalyzed sylylation of alkenes with chlorosilanes
    Terao, J
    Torii, K
    Saito, K
    Kambe, N
    Baba, A
    Sonoda, N
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1998, 37 (19) : 2653 - 2656
  • [39] Scope of the intramolecular titanocene-catalyzed Pauson-Khand type reaction
    Hicks, FA
    Kablaoui, NM
    Buchwald, SL
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (25) : 5881 - 5898
  • [40] PREPARATION OF CONJUGATED DIENES AND ETHYLIDENECYCLOALKANES BY DOUBLE-BOND SHIFT CATALYZED BY TITANOCENE DERIVATIVES
    MACH, K
    TURECEK, F
    ANTROPIUSOVA, H
    PETRUSOVA, L
    HANUS, V
    SYNTHESIS-STUTTGART, 1982, (01): : 53 - 55
12345