Synthesis and crystal structure of N,N′-(p-phenyl)-bis-(p-nitro)benzoylthiourea

被引：11

作者：

Dong, Wen-Kui ^{[1
]}

Yang, Xiao-Qing ^{[1
]}

Chai, Lan-Qin ^{[1
]}

Tian, Yong-Qiang ^{[1
]}

Feng, Jian-Hua ^{[1
]}

机构：

[1] Lanzhou Jiaotong Univ, Sch Chem & Biol Engn, Lanzhou 730070, Gansu, Peoples R China

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2008年 / 183卷 / 05期

关键词：

crystal structure; N; '-(p-phenyl)-bis-(p-nitro)benzoylthiourea; synthesis; X-ray diffraction;

D O I：

10.1080/10426500701610952

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

N, N'-(p-phenyl)-bis-(p-nitro)benzoylthiourea was synthesized and characterized by elemental analysis as well as IR and H-1 NMR spectroscopy. The crystal structure of the title compound was determined by single crystal X-ray diffraction. It was crystallized in triclinic space group of P-1, a = 8.1084(12), b = 11.9185(13), c = 12.6061(15) angstrom, alpha = 62.213(2)degrees, beta = 71.266(2)degrees, gamma = 88.014(3)degrees, Z = 1, V = 1011.0(2)angstrom(3) . The intramolecular N-H center dot center dot center dot O hydrogen bonding interactions between the N-H and the oxygen atom of C=O groups suport N, N'-(p-phenyl)-bis-(p-nitro)benzoylthiourea framework. the solvent DMF molecules are accommodated in the framework by intermolecular N-H center dot center dot center dot O hydrogen bonds between N-H and the oxygen atom of DMF in the title compound, which help to assemble into supramolecular structure.

引用

页码：1181 / 1187

页数：7

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