High glucose yields from the hydrolysis of cellulose dissolved in ionic liquids

被引：75

作者：

Morales-delaRosa, Silvia ^{[1
]}

Campos-Martin, Jose M. ^{[1
]}

Fierro, Jose L. G. ^{[1
]}

机构：

[1] CSIC, Inst Catalisis & Petr Quim, Sustainable Energy & Chem Grp, Madrid 28049, Spain

来源：

CHEMICAL ENGINEERING JOURNAL | 2012年 / 181卷

关键词：

Cellulose; Hydrolysis; Ionic liquid; Glucose; Acid; LIGNOCELLULOSIC BIOMASS; FERMENTABLE SUGARS; BIOETHANOL; BIOFUELS; ACID;

D O I：

10.1016/j.cej.2011.11.061

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Here we show a method to hydrolyze cellulose selectively to glucose and cellobiose. sugars that can be easily fermented. Selecting an ideal ionic liquid ([EMIM]Cl), optimizing the dissolution time/temperature (15 min, 408 K) and the reaction procedure (addition of water during the reaction time) led to a very high selectivity to glucose + cellobiose (99.6%). (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：538 / 541

页数：4

共 50 条

[31] Cellulose regeneration and spinnability from ionic liquids
Hauru, Lauri K. J.
Hummel, Michael
Nieminen, Kaarlo
Michud, Anne
Sixta, Herbert
SOFT MATTER, 2016, 12 (05) : 1487 - 1495
[32] Hydrolysis and Decomposition of Cellulose in Bronsted Acidic Ionic Liquids Under Mild Conditions
Amarasekara, Ananda S.
Owereh, Onome S.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2009, 48 (22) : 10152 - 10155
[33] Hydrolysis of Cellulose by Using Catalytic Amounts of FeCl2 in Ionic Liquids
Tao, Furong
Song, Huanling
Chou, Lingjun
CHEMSUSCHEM, 2010, 3 (11) : 1298 - 1303
[34] Hydrolysis of cellulose to produce glucose in ionic liquid-water mixtures
Xu, Tianjiao
Chen, Jinyang
Ji, Yimei
ADVANCES IN CHEMICAL, MATERIAL AND METALLURGICAL ENGINEERING, PTS 1-5, 2013, 634-638 : 873 - 876
[35] Homogenous hydrolysis of cellulose to glucose in an inorganic ionic liquid catalyzed by zeolites
Tao Wu
Ning Li
Xuejun Pan
Sheng-Li Chen
Cellulose, 2020, 27 : 9201 - 9215
[36] Homogenous hydrolysis of cellulose to glucose in an inorganic ionic liquid catalyzed by zeolites
Wu, Tao
Li, Ning
Pan, Xuejun
Chen, Sheng-Li
CELLULOSE, 2020, 27 (16) : 9201 - 9215
[37] Partial enzymatic hydrolysis of microcrystalline cellulose in ionic liquids by Trichoderma reesei endoglucanases
Wahlstrom, Ronny
Rovio, Stella
Suurnakki, Anna
RSC ADVANCES, 2012, 2 (10) : 4472 - 4480
[38] Membrane-based recovery of glucose from enzymatic hydrolysis of ionic liquid pretreated cellulose
Abels, Christian
Thimm, Kristof
Wulfhorst, Helene
Spiess, Antje Christine
Wessling, Matthias
BIORESOURCE TECHNOLOGY, 2013, 149 : 58 - 64
[39] Hydrolysis of regenerated cellulose from ionic liquids and deep eutectic solvent over sulfonated carbon catalysts
Kim, Han Ung
Kim, Jong Wha
Seo, Sumin
Jae, Jungho
RSC ADVANCES, 2023, 13 (12) : 8153 - 8162
[40] High yields of sugars via the non-enzymatic hydrolysis of cellulose
Berberi, V.
Turcotte, F.
Lantagne, G.
Chornet, M.
Lavoie, J. -M.
ENERGY AND SUSTAINABILITY III, 2011, 143 : 87 - +

← 1 2 3 4 5 →