Insertion of dihalocarbenes into Ge-H and Sn-H bonds under phase transfer catalysis conditions

被引:0
|
作者
Abele, E [1 ]
Rubina, K [1 ]
Arsenyan, P [1 ]
Popelis, Y [1 ]
Grinberga, S [1 ]
Mishnev, A [1 ]
Lukevics, E [1 ]
机构
[1] Latvian Inst Organ Synth, LV-1006 Riga, Latvia
来源
MAIN GROUP METAL CHEMISTRY | 1999年 / 22卷 / 01期
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中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The reaction of hydrostannanes and germanes with dihalocarbenes generated from haloforms or from sodium trichloroacetate under phase transfer conditions was studied. The dihalomethyl trialkyl stannanes and germanes were obtained with isolated yield up to 86%.
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页码:65 / 70
页数:6
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