Acene-Extended Triptycenes: Synthesis, Characterization, and Singlet Exciton Fission Properties

被引：0

作者：

Duan, Yuxiao ^{[1
]}

Zhang, Guowei ^{[1
]}

Liu, Xinyue ^{[1
]}

Shi, Fenghui ^{[2
]}

Wang, Tingting ^{[2
]}

Yan, Hongchen ^{[2
]}

Xu, Hu ^{[2
]}

Zhang, Lei ^{[1
]}

机构：

[1] Beijing Univ Chem Technol, Beijing Adv Innovat Ctr Soft Matter Sci & Engn, Beijing 100029, Peoples R China

[2] AVIC Mfg Technol Inst, Composite Technol Ctr, Beijing 101300, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 87卷 / 14期

基金：

中国国家自然科学基金;

关键词：

FREE-VOLUME; POLYMER; DELOCALIZATION; DESIGN; MODELS; DIMERS;

D O I：

10.1021/acs.joc.1c026938841J

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Three acene-extended triptycenes, TIPS-Antrip, TIPS-Tetrip, and TIPS-Pentrip, which contain TIPS-ethynyl functionalized anthracene, tetracene, and pentacene as subunits, respectively, are synthesized and characterized. It is found that the optoelectronic properties and crystal packing motifs could be modulated by changing the subunits. A preliminary exploration of the excited-state behavior of these molecules indicates that TIPS-Tetrip and TIPS-Pentrip exhibit intramolecular singlet fission (iSF).

引用

页码：8841 / 8848

页数：8

共 39 条

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