{(E)-4-[(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino-methyl]benzoato}triphenyltin(IV)

被引:1
|
作者
Fang, Xiao-Niu [1 ]
Sui, Yan [1 ]
Hu, Rong-Hua [1 ]
Luo, Qiu-Yan [1 ]
Qin, Hai-Qiong [1 ]
机构
[1] JingGangShan Univ, Coll Chem & Chem Engn, Jian 343009, Jiangxi, Peoples R China
关键词
D O I
10.1107/S1600536807027298
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, [Sn(C6H5) (3)(C19H16N3O3)], is a fourcoordinate Sn-IV complex, with a distorted tetrahedral geometry and one disordered ( 0.54: 0.46) phenyl ring. The Schiff base carboxylate group acts as a monodentate ligand coordinating through the deprotonated hydroxyl O atom. In the crystal structure, a weak offset face-to-face aromatic pi-pi stacking interaction can be found between the pyrazole ring and the benzene ring of 4-formylbenzoic acid. The centroid-to-centroid distance is 3.858 (2) angstrom and the interplanar distance is 3.375 (4) angstrom.
引用
收藏
页码:M1843 / U611
页数:12
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