Copper-Catalyzed Cross-Coupling Reaction of Organoboron Compounds with Primary Alkyl Halides and Pseudohalides

被引：179
|
作者：
Yang, Chu-Ting [1 ]
Zhang, Zhen-Qi [1 ]
Liu, Yu-Chen [1 ]
Liu, Lei [1 ]
机构：
[1] Tsinghua Univ, Dept Chem, Minist Educ, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Beijing 100084, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 17期
关键词：
alkyl halides; alkyl pseudohalides; copper; cross-coupling; organoboron compounds; GRIGNARD-REAGENTS; ROOM-TEMPERATURE; SUZUKI REACTIONS; BETA-HYDROGENS; ARYL IODIDES; BROMIDES; CHLORIDES; ELECTROPHILES; CU; NUCLEOPHILES;
D O I：
10.1002/anie.201008007
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Non-activated alkyl electrophiles, including alkyl iodides, bromides, tosylates, mesylates, and even chlorides, underwent copper-catalyzed cross-coupling with aryl boron compounds and alkyl 9-BBN reagents (see scheme; 9-BBN=9-borabicyclo[3.3.1]nonane). The reactions proceed with practically useful reactivities and thus complement palladium- and nickel-catalyzed Suzuki-Miyaura coupling reactions of alkyl halides. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：3904 / 3907
页数：4
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