Stereoselective reduction of the C4 carbonyl group of methyl 2,3,6-tri-O-methyl-α-D-xylo-hexopyranosid-4-ulose.: Synthesis of methyl 2,3,4-tri-O-methyl-α-D-galactopyranoside

被引：0

作者：

Yeagley, D ^{[1
]}

Miljkovic, M ^{[1
]}

机构：

[1] Penn State Univ, Milton S Hershey Med Ctr, Dept Biochem & Mol Biol, Hershey, PA 17033 USA

来源：

JOURNAL OF THE SERBIAN CHEMICAL SOCIETY | 1998年 / 63卷 / 06期

关键词：

synthesis; stereoselective reduction; methyl 2,3,6-tri-O-methyl-alpha-D-galactopyranoside;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reduction of methyl 2,3,6-tri-O-methyl-alpha-D-xylo-hexopyranosid-4-ulose with lithium tri-sec-butylborohydride gave methyl 2,3,6-tri-O-methyl-alpha-D-galactopyranoside as the only detectable product. Reduciton of 1 by lithium aluminum hydride gave a mixture of corresponding D-gluco-and D-galacto-derivatives in 3:4 ratio.

引用

页码：439 / 443

页数：5

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