Scalable electrochemical oxidant-and metal-free dehydrogenative coupling of S-H/N-H

被引：36

作者：

Tang, Shanyu ^{[1
]}

Liu, Yan ^{[2
]}

Li, Longjia ^{[1
]}

Ren, Xuanhe ^{[1
]}

Li, Jiao ^{[1
]}

Yang, Guanyu ^{[1
]}

Li, Heng ^{[1
]}

Yuan, Bingxin ^{[1
]}

机构：

[1] Zhengzhou Univ, Dept Chem & Mol Engn, Zhengzhou 450001, Henan, Peoples R China

[2] Zhengzhou Univ, Sch Life Sci, Zhengzhou 450001, Henan, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2019年 / 17卷 / 06期

基金：

中国国家自然科学基金;

关键词：

C-H; OXIDATION; SULFENAMIDES; THIOLS; WATER; STRATEGIES; AMINES; ALKYL; BOND;

D O I：

10.1039/c8ob03211d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A practical and scalable electrochemical oxidation of S-H and N-H was developed. This oxidant-and catalyst-free electrochemical process enables S-N bond formation with inexpensive nickel electrodes in an undivided cell. This procedure exhibits broad substrate scopes and good functional-group compatibility. A 50 g scale oxidative coupling augurs well for industrial applications.

引用

页码：1370 / 1374

页数：5

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