Scalable electrochemical oxidant-and metal-free dehydrogenative coupling of S-H/N-H

被引：36
|
作者：
Tang, Shanyu [1 ]
Liu, Yan [2 ]
Li, Longjia [1 ]
Ren, Xuanhe [1 ]
Li, Jiao [1 ]
Yang, Guanyu [1 ]
Li, Heng [1 ]
Yuan, Bingxin [1 ]
机构：
[1] Zhengzhou Univ, Dept Chem & Mol Engn, Zhengzhou 450001, Henan, Peoples R China
[2] Zhengzhou Univ, Sch Life Sci, Zhengzhou 450001, Henan, Peoples R China
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2019年 / 17卷 / 06期
基金：
中国国家自然科学基金;
关键词：
C-H; OXIDATION; SULFENAMIDES; THIOLS; WATER; STRATEGIES; AMINES; ALKYL; BOND;
D O I：
10.1039/c8ob03211d
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A practical and scalable electrochemical oxidation of S-H and N-H was developed. This oxidant-and catalyst-free electrochemical process enables S-N bond formation with inexpensive nickel electrodes in an undivided cell. This procedure exhibits broad substrate scopes and good functional-group compatibility. A 50 g scale oxidative coupling augurs well for industrial applications.
引用
收藏
页码：1370 / 1374
页数：5
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