In situ generation of palladium nanoparticles: A simple and highly active protocol for oxygen-promoted ligand-free suzuki coupling reaction of aryl chlorides

被引：161
|
作者：
Han, Wei [1 ]
Liu, Chun [1 ]
Jin, Zi-Lin [1 ]
机构：
[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China
来源：
ORGANIC LETTERS | 2007年 / 9卷 / 20期
关键词：
EFFICIENT CATALYSTS; PHENYLBORONIC ACID; ARYLBORONIC ACIDS; BOND FORMATION; CARBON-CARBON; C-C; MIYAURA; BROMIDES; SONOGASHIRA; COMPLEXES;
D O I：
10.1021/ol701709q
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An oxygen-promoted ligand-free Suzuki coupling reaction catalyzed by in situ generated palladium nanoparticles in PEG-400 under aerobic conditions has been demonstrated. The reaction was highly efficient for coupling aryl chlorides with phenylboronic acid in short times under mild conditions.
引用
收藏
页码：4005 / 4007
页数：3
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