An investigation of the first-order spin-state transition in Fe(Phen)(2)(NCS)(2) EXAFS and infrared spectroscopy

被引：13
|
作者：
Sankar, G
Thomas, JM
Varma, V
Kulkarni, GU
Rao, CNR
机构：
[1] INDIAN INST SCI, SOLID STATE & STRUCT CHEM UNIT, BANGALORE 560012, KARNATAKA, INDIA
[2] UCL ROYAL INST GREAT BRITAIN, DAVY FARADAY LAB, LONDON WX1 4BS, ENGLAND
[3] UNIV WALES COLL CARDIFF, DEPT CHEM, CARDIFF CF1 3TB, S GLAM, WALES
来源：
CHEMICAL PHYSICS LETTERS | 1996年 / 251卷 / 1-2期
基金：
英国工程与自然科学研究理事会;
关键词：
D O I：
10.1016/0009-2614(96)00071-1
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The structure of Fe(Phen)(2)(NCS)(2) has been examined across the first-order spin-state transition by EXAFS with full multiple scattering analysis. The EXAFS data at 298 K can be satisfactorily assigned to the high-spin state, but the analysis of the low-temperature data at 90 K is not entirely unequivocal, although consistent with the predominant presence of the low-spin state. That some proportion of the high-spin state remains at low temperatures, well below the first-order transition, is clearly evidenced in the infrared spectra, suggesting possible sublattice ordering.
引用
收藏
页码：79 / 83
页数：5
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