cis-Dichlorobis(2,2′-biquinoline)iridium(III) hexafluorophosphate

被引：5

作者：

Yoshikawa, N ^{[1
]}

Sakamoto, J

Kanehisa, N

Kai, Y

Matsumura-Inoue, T

Takashima, H

Tsukahara, K

机构：

[1] Nara Womens Univ, Fac Sci, Dept Chem, Nara 6308506, Japan

[2] Nara Univ Educ, Dept Chem, Nara 6308528, Japan

[3] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Osaka 5650871, Japan

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2003年 / 59卷

关键词：

D O I：

10.1107/S1600536803014235

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal structure of the title compound, [IrCl2(bqn)(2)]PF6, (bqn is 2,2'-biquinoline, C18H12N2), contains a monomeric [IrCl2(bqn)(2)](+) cation and a hexafluorophosphate anion. The iridium(III) ion is coordinated by four N atoms from two bqn ligands [mean Ir-N distance 2.065 (5) Angstrom] and two Cl atoms [Ir-Cl=2.342 (2) and 2.353 (2) Angstrom], forming a distorted octahedral environment. Each 2,2'-biquinoline ligand is planar, the mean deviations from the least-squares planes being 0.2431 (6) and 0.1665 (6) Angstrom.

引用

页码：M551 / M552

页数：2

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