cis-Dichlorobis(2,2′-biquinoline)iridium(III) hexafluorophosphate

被引：5
|
作者：
Yoshikawa, N [1 ]
Sakamoto, J
Kanehisa, N
Kai, Y
Matsumura-Inoue, T
Takashima, H
Tsukahara, K
机构：
[1] Nara Womens Univ, Fac Sci, Dept Chem, Nara 6308506, Japan
[2] Nara Univ Educ, Dept Chem, Nara 6308528, Japan
[3] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Osaka 5650871, Japan
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2003年 / 59卷
关键词：
D O I：
10.1107/S1600536803014235
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The crystal structure of the title compound, [IrCl2(bqn)(2)]PF6, (bqn is 2,2'-biquinoline, C18H12N2), contains a monomeric [IrCl2(bqn)(2)](+) cation and a hexafluorophosphate anion. The iridium(III) ion is coordinated by four N atoms from two bqn ligands [mean Ir-N distance 2.065 (5) Angstrom] and two Cl atoms [Ir-Cl=2.342 (2) and 2.353 (2) Angstrom], forming a distorted octahedral environment. Each 2,2'-biquinoline ligand is planar, the mean deviations from the least-squares planes being 0.2431 (6) and 0.1665 (6) Angstrom.
引用
收藏
页码：M551 / M552
页数：2
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