2-(2-Pyridyl)pyridinium bis(pyridine-2,6-dicarboxylato-κ2O2, O6)iron(III) trihydrate

被引：5
|
作者：
Zhao, QH [1 ]
Zhang, MS [1 ]
Fang, RB [1 ]
机构：
[1] Yunnan Univ, Dept Chem, Ctr Adv Studies Med & Organ Chem, Kunming 650091, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2005年 / 61卷
关键词：
D O I：
10.1107/S1600536805036469
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, (C10H9N2)[Fe(C7H3NO4)(2)]center dot 3H(2)O, was prepared from the ligand pyridine-2,6-dicarboxylic acid with FeCl(3)center dot 6H(2)O in the presence of 2,2-bipyridine. The Fe-III atom is six-coordinate in a distorted octahedral geometry. The compound contains protonated 2,2'-bipyridine and doubly deprotonated pyridine-2,6-dicarboxylate (pydc) units; the protonated 2,2'-bipyridine bridges adjacent [Fe( pydc)(2)](-) complex units through hydrogen bonding.
引用
收藏
页码：M2575 / M2577
页数：3
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