Three-Dimensional Network Structures Based on Pyridyl-Calix[4]Arene Metal Complexes

被引：7

作者：

Sgarlata, Carmelo ^{[1
]}

Brancatelli, Giovanna ^{[2
]}

Fortuna, Cosimo G. ^{[1
]}

Sciotto, Domenico ^{[1
]}

Geremia, Silvano ^{[2
]}

Bonaccorso, Carmela ^{[1
]}

机构：

[1] Univ Catania, OrgDiv, Dipartimento Sci Chim, Viale A Doria 6, I-95125 Catania, Italy

[2] Univ Trieste, Dipartimento Sci Chim & Farmaceut, Ctr Eccellenza Biocristallog, Via L Giorgieri 1, I-34127 Trieste, Italy

来源：

CHEMPLUSCHEM | 2017年 / 82卷 / 11期

关键词：

calixarenes; metal-directed assemblies; self-assembly; solid-state structures; titrations; MOLECULAR RECOGNITION; DIMERIC CAPSULES; BUILDING-BLOCKS; GEMINI GUESTS; CALIXARENE; WATER; THERMODYNAMICS; EQUILIBRIUM; MACROCYCLES; CAVITANDS;

D O I：

10.1002/cplu.201700400

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new series of supramolecular assemblies is obtained through the interaction of 3-pyridylmethyl-calixarenes and copper or zinc ions. The complexes formed are characterized both in solution and in the solid state. The results offer appealing insights into how the steric crowding of the lower rim and different coordination modes of the metal centers have a great impact on the overall architecture of the complexes with the formation of monomeric, dimeric, or oligomeric/polymeric species.

引用

页码：1341 / 1350

页数：10

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