Synthesis and crystal structure of a rare square-planar Co(II) complex of a hydroxyamidinate ligand

被引：20

作者：

Cibian, Mihaela ^{[1
]}

Derossi, Sofia ^{[1
]}

Hanan, Garry S. ^{[1
]}

机构：

[1] Univ Montreal, Dept Chim, Montreal, PQ H3T 1J4, Canada

来源：

DALTON TRANSACTIONS | 2011年 / 40卷 / 05期

基金：

加拿大自然科学与工程研究理事会;

关键词：

SOLAR-CELLS; COBALT; IRON;

D O I：

10.1039/c0dt01365j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel hydroxyamidinate complexes of cobalt(II) are presented, together with their electrochemical and spectroscopic properties. An unusual d(7) square-planar coordination around the cobalt(II) center exists and was confirmed by chemical oxidation to its Co(III) species. The Co(II) complex is difficult to reduce, but its facile oxidation suggests that it may be useful as an electron donor in photoredox reactions.

引用

页码：1038 / 1040

页数：3

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