UV-Vis and ESI MS/MS Study of Calix[4]arene Derivatives and Their Lanthanide Complexes

被引：5
|
作者：
Bakic, Marina Tranfic [1 ]
Soledad Espinosa, Mariela [2 ]
Cindro, Nikola [3 ]
Frkanec, Leo [4 ]
Alejandra Babay, Paola [2 ]
Galic, Nives [3 ]
机构：
[1] Univ Zagreb, Dept Chem & Biochem, Fac Food Technol & Biotechnol, Pierottijeva 6, Zagreb 10000, Croatia
[2] Natl Commiss Atom Energy, Dept Analyt Chem, Av Gral Paz 1499, Buenos Aires, DF, Argentina
[3] Univ Zagreb, Fac Sci, Dept Chem, Horvatovac 102a, Zagreb 10000, Croatia
[4] Rudjer Boskovic Inst, Dept Organ Chem & Biochem, Bijenicka C 54, HR-10000 Zagreb, Croatia
来源：
CROATICA CHEMICA ACTA | 2017年 / 90卷 / 04期
关键词：
calixarenes; lanthanides; electrospray mass spectrometry; UV-Vis spectroscopy; ALKALI-METAL CATIONS; LOWER-RIM; AMIDE DERIVATIVES; TERTIARY AMIDE; EXTRACTION; CALIXARENES; THERMODYNAMICS; DIGLYCOLAMIDE; RECOGNITION; BINDING;
D O I：
10.5562/cca3288
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Coordination properties of calix[4]arenes bearing substituents on the lower rim: tetraethyl ester (1), tetraethylamide (2), and newly synthesized tetraethylmethylamide derivative (3), towards selected lanthanide cations (La3+, Eu3+, Yb3+) were studied by spectrophotometric titrations. No complexation was observed with ester derivative, while amide derivatives formed 1:1 complexes and bound lanthanide cations very efficiently (lgK(La2) = 5.1; lgK(Eu2) >= 6; lgK(Yb2) >= 6; lgK(La3) >= 6; lgK(Eu3) >= 6; lgK(Yb3) >= 6). The ligands and complexes were also analysed by ESI MS and MS/MS spectrometry. Both inductive cleavage and proton rearrangement fragmentation reactions were observed. Corresponding fragmentation pathways were proposed. The results obtained by MS analysis were in accordance with those obtained by spectrophotometric titrations.
引用
收藏
页码：679 / 687
页数：9
相关论文
共 50 条
  • [31] Theoretical Study on Structures and UV-Vis Spectra of Macrocyclic Thiophene Derivatives
    Huang Shuang
    Ren Ai-Min
    Li Zhuo
    Zhao Yang
    Min Chun-Gang
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2010, 31 (03): : 553 - 558
  • [32] UV-Vis absorption study of some tetragonal chromium (III) complexes
    Schatschneider, B
    Perumareddi, JR
    INORGANICA CHIMICA ACTA, 2005, 358 (15) : 4571 - 4574
  • [33] UV-VIS study of the inclusion complexes of oxolinic acid with cyclodextrins.
    Leyva-Guerrero, E
    Monreal, E
    Moctezuma, E
    Tovar, E
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 221 : U155 - U155
  • [34] Characterization and discrimination of saffron by multisensory systems, SPME-GC-MS and UV-Vis spectrophotometry
    Tahri, K.
    Tiebe, C.
    Bougrini, M.
    Saidi, T.
    El Hassani, N. El Alami
    El Bari, N.
    Huebert, T.
    Bouchikhi, B.
    ANALYTICAL METHODS, 2015, 7 (24) : 10328 - 10338
  • [35] Extraction and complexation of lanthanide ions by dihomooxacalix[4]arene and calix[4]arene tetraketone derivatives: An experimental and molecular dynamics investigation
    Fonseca, Joel D.
    Marcos, Paula M.
    Ascenso, Jose R.
    Michel, Sylvia
    Hubscher-Bruder, Veronique
    Schurhammer, Rachel
    COMPTES RENDUS CHIMIE, 2019, 22 (9-10) : 639 - 647
  • [36] ESI(+)-MS and GC-MS Study of the Hydrolysis of N-Azobenzyl Derivatives of Chitosan
    Pereira, Fernanda S.
    Nascimento, Heliara D. L.
    Magalhaes, Alvicler
    Peter, Martin G.
    Bataglion, Giovana Anceski
    Eberlin, Marcos N.
    Gonzalez, Eduardo R. P.
    MOLECULES, 2014, 19 (11): : 17604 - 17618
  • [37] Optical and electrical study of chromogenic calix[4]arene derivatives
    Rouis, A
    Dridi, C
    Ben Chaabane, R
    Davenas, J
    Aeiyach, S
    Ben Ouada, H
    Dumazet-Bonnamour, I
    Halouani, H
    MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS, 2006, 26 (2-3): : 240 - 246
  • [38] UV-Vis and NMR spectroscopic investigations on effective and selective non-covalent interactions between fullerenes and calix[6]arene
    Halder, Amal
    Nayak, Sandip K.
    Chattopadhyay, Subrata
    Bhattacharya, Sumanta
    JOURNAL OF MOLECULAR LIQUIDS, 2010, 151 (2-3) : 125 - 129
  • [39] Click synthesis of triazole-linked calix[4]arene ionophores. Potentiometric and ESI-MS screening of ion-selectivity
    János B. Czirok
    Gyula Jágerszki
    Klára Tóth
    Ágnes Révész
    László Drahos
    István Bitter
    Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2014, 78 : 207 - 215
  • [40] Click synthesis of triazole-linked calix[4]arene ionophores. Potentiometric and ESI-MS screening of ion-selectivity
    Czirok, Janos B.
    Jagerszki, Gyula
    Toth, Klara
    Revesz, Agnes
    Drahos, Laszlo
    Bitter, Istvan
    JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2014, 78 (1-4) : 207 - 215
12345