Separation of thorium from uranium ore

被引:7
|
作者
Kmak, Kelly N. [1 ]
Shaughnessy, Dawn A. [2 ]
Vujic, Jasmina [1 ]
机构
[1] Univ Calif Berkeley, Dept Nucl Engn, Berkeley, CA 94720 USA
[2] Lawrence Livermore Natl Lab, Nucl & Chem Sci Div, Livermore, CA 94550 USA
关键词
Uranium ore; Th-230; Liquid-liquid separation; Ion exchange chromatography; SOLVENT-EXTRACTION; RECOVERY; TH-230; TBP; TH;
D O I
10.1007/s10967-019-06980-1
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Thorium-230 has many research applications, but there is not a commercial source of this isotope. However, since Th-230 is part of the U-238 decay chain, it can be separated from naturally occurring uranium. In this work, a novel procedure was developed to separate thorium from uranium ore, consisting of leaching, liquid-liquid extraction, precipitations and ion exchange chromatography. The final product was 91.32 +/- 0.77 mg of thorium with a purity of 99.5 +/- 1.2 wt%. Of that, 7.65 +/- 0.10 mg was Th-230 and the remainder Th-232. The total yield of Th-230 was 71.1 +/- 5.4%. Ways to improve the yield by further processing the back-extraction solution are suggested.
引用
收藏
页码:931 / 945
页数:15
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