A new stereoselective synthesis of chiral gamma-functionalized (E)-allylic amines

被引：49
|
作者：
Reginato, G
Mordini, A
Messina, F
Degl'Innocenti, A
Poli, G
机构：
[1] CNR-Centro di Stud. Sulla Chim. e S., Dipto. di Chimica Organica U. Schiff, 50121 Firenze
来源：
TETRAHEDRON | 1996年 / 52卷 / 33期
关键词：
D O I：
10.1016/0040-4020(96)00617-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Chiral t-Boc protected propargylic amines have been obtained starting from aminoaldehydes derived from natural aminoacids. Stannylcupration of these substrates affords an easy regio- and stereocontrolled route to the corresponding gamma-stannylated (E)-allylamines which are useful intermediates for the synthesis of the corresponding gamma-funtionalized allylic systems. Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码：10985 / 10996
页数：12
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