A Nano-Architectured Metal-Oxide/Perovskite Hybrid Material as Electrocatalyst for the Oxygen Reduction Reaction in Aluminum-Air Batteries

被引:21
|
作者
Xue, Yejian [1 ]
Yan, Shanshan [1 ,2 ]
Huang, Heran [1 ]
Liu, Zhaoping [1 ]
机构
[1] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Zhejiang, Peoples R China
[2] Yanshan Univ, Coll Environm & Chem Engn, Hebei Key Lab Appl Chem, Qinhuangdao 066004, Peoples R China
关键词
aluminum-air battery; composite material; electrocatalyst; oxygen reduction reaction; transition-metal oxide catalysts; perovskite; HIGHLY EFFICIENT ELECTROCATALYST; PEROVSKITE OXIDE; BIFUNCTIONAL CATALYST; EVOLUTION REACTIONS; FUEL-CELLS; CARBON; NANOPARTICLES; CATHODE; SURFACE; LA2O3;
D O I
10.1021/acsanm.8b01630
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A nanoarchitectured La2O2CO3-La0.7Sr0.3MnO3 hybrid catalyst is prepared by a facile hydrothermal method. The La2O2CO3 nanorods are well distributed on the regular hexagonal La0.7Sr0.3MnO3 nanosheet. The La2O2CO3-La0.7Sr0.3MnO3 catalyst has better catalytic activity to oxygen reduction reaction than that of La2O2CO3 or La0.7Sr0.3MnO3. The reaction kinetics result shows that La2O2CO3-La0.7Sr0.3MnO3 sample follows a four-electron transferred process during the oxygen reduction reaction. Furthermore, the stability of La2O2CO3-La0.7Sr0.3MnO3 is higher than that of Pt/C. By using La2O2CO3-La0.7Sr0.3MnO3 as the cathode catalysts for aluminumair battery, the power densities can reach 223.8 mW cm(2). The high catalytic performance of the La2O2CO3-La0.7Sr0.3MnO3 can be attributed to the strong interaction between the La2O2CO3 material and La0.7Sr0.3MnO3 material.
引用
收藏
页码:6824 / 6833
页数:19
相关论文
共 50 条
  • [41] Plasma-engineered cobalt nanoparticle encapsulated N-doped graphene nanoplatelets as high-performance oxygen reduction reaction electrocatalysts for aluminum-air batteries
    Jeong, Soyoon
    Kim, Seonghee
    Son, Hyunjee
    Li, Oi Lun
    CATALYSIS TODAY, 2023, 420
  • [42] Donor-acceptor iron phthalocyanine-based hyper-crosslinked polymers with a modulated electronic structure for efficient oxygen reduction reaction in aluminum-air batteries
    Dong, Xinran
    Luo, Yingjian
    Tao, Shuhui
    Liu, Jiayao
    Tan, Xing
    Lu, Ze
    Wang, Gang
    Chen, Jinwei
    Wang, Ruilin
    Zhang, Jie
    JOURNAL OF MATERIALS CHEMISTRY A, 2024, 12 (23) : 13800 - 13809
  • [43] Enhanced electronic interaction between iron phthalocyanine and cobalt single atoms promoting oxygen reduction in alkaline and neutral aluminum-air batteries
    Wang, Yibo
    Li, Kaiqi
    Cheng, Ruiqi
    Xue, Qingyue
    Wang, Fei
    Yang, Zhaohui
    Meng, Pengyu
    Jiang, Min
    Zhang, Jiao
    Fu, Chaopeng
    CHEMICAL ENGINEERING JOURNAL, 2022, 450
  • [44] A Hybrid Material Combined Copper Oxide with Graphene for an Oxygen Reduction Reaction in an Alkaline Medium
    Yu, Jiemei
    Huang, Taizhong
    Jiang, Zhankun
    Sun, Min
    Tang, Chengchun
    MOLECULES, 2019, 24 (03)
  • [45] Co-SrCO3/N-doped carbon: a highly efficient hybrid electrocatalyst for the oxygen reduction reaction and Zn-air batteries
    He, Xiaobo
    Yin, Fengxiang
    Chen, Jinnan
    Ye, Caiyun
    INORGANIC CHEMISTRY FRONTIERS, 2017, 4 (06): : 1073 - 1086
  • [46] Simple Fabrication of Titanium Dioxide/N-Doped Carbon Hybrid Material as Non-Precious Metal Electrocatalyst for the Oxygen Reduction Reaction
    Jin, Shangbin
    Li, Cuiling
    Shrestha, Lok Kumar
    Yamauchi, Yusuke
    Ariga, Katsuhiko
    Hill, Jonathan P.
    ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (22) : 18782 - 18789
  • [47] Selection of oxygen reduction catalysts for rechargeable lithium-air batteries-Metal or oxide?
    Cheng, H.
    Scott, K.
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2011, 108 (1-2) : 140 - 151
  • [48] Nano-Co-embedded carbon nanofibers for oxygen reduction reaction in Zn-air batteries
    Sun, Tiantian
    Chen, Xinyu
    Li, Suriguga
    Xu, Dan
    Wang, Heng-guo
    MATERIALS CHEMISTRY AND PHYSICS, 2023, 296
  • [49] MnO/N-Doped Mesoporous Carbon as Advanced Oxygen Reduction Reaction Electrocatalyst for Zinc-Air Batteries
    Ding, Jieting
    Ji, Shan
    Wang, Hui
    Brett, Dan J. L.
    Pollet, Bruno G.
    Wang, Rongfang
    CHEMISTRY-A EUROPEAN JOURNAL, 2019, 25 (11) : 2868 - 2876
  • [50] La1-xAgxMnO3 electrocatalyst with high catalytic activity for oxygen reduction reaction in aluminium air batteries
    Xue, Yejian
    Miao, He
    Sun, Shanshan
    Wang, Qin
    Li, Shihua
    Liu, Zhaoping
    RSC ADVANCES, 2017, 7 (09): : 5214 - 5221