A new near-infrared-responsive photocatalyst of NaYF4:Yb,Tm@Cu2O have been successfully synthesized by a simple method. Methylene blue as a model pollutant was used to study the photocatalytic activity of NaYF4:Yb,Tm@Cu2O composites, and the energy transfer process between NaYF4:Yb, Tm and Cu2O and the origin of the degradation of pollutants were investigated. It was found that the energy transfer route between NaYF4:Yb, Tm and Cu2O is an important factor for the overall photocatalytic activity. This study suggests a promising system to apply upconversion materials for utilizing the near-infrared light to irradiate Cu2O-based photocatalysts.
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Korea Inst Sci & Technol, Mat Architecturing Res Ctr, 5 Hwarang Ro 14 Gil, Seoul 02792, South KoreaKorea Inst Sci & Technol, Mat Architecturing Res Ctr, 5 Hwarang Ro 14 Gil, Seoul 02792, South Korea
Hong, A-Ra
Shin, Seungyong
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Korea Inst Sci & Technol, Mat Architecturing Res Ctr, 5 Hwarang Ro 14 Gil, Seoul 02792, South KoreaKorea Inst Sci & Technol, Mat Architecturing Res Ctr, 5 Hwarang Ro 14 Gil, Seoul 02792, South Korea
Shin, Seungyong
Kang, Gumin
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Korea Inst Sci & Technol, Nanophoton Res Ctr, 5 Hwarang Ro 14 Gil, Seoul 02792, South KoreaKorea Inst Sci & Technol, Mat Architecturing Res Ctr, 5 Hwarang Ro 14 Gil, Seoul 02792, South Korea
Kang, Gumin
Ko, Hyungduk
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Korea Inst Sci & Technol, Nanophoton Res Ctr, 5 Hwarang Ro 14 Gil, Seoul 02792, South KoreaKorea Inst Sci & Technol, Mat Architecturing Res Ctr, 5 Hwarang Ro 14 Gil, Seoul 02792, South Korea
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Univ Massachusetts, Sch Med, Dept Biochem & Mol Pharmacol, Worcester, MA 01605 USAUniv Massachusetts, Sch Med, Dept Biochem & Mol Pharmacol, Worcester, MA 01605 USA
Shen, Jie
Chen, Guanying
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SUNY Buffalo, Dept Chem, Inst Lasers Photon & Biophoton, Buffalo, NY 14260 USAUniv Massachusetts, Sch Med, Dept Biochem & Mol Pharmacol, Worcester, MA 01605 USA
Chen, Guanying
Ohulchanskyy, Tymish Y.
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SUNY Buffalo, Dept Chem, Inst Lasers Photon & Biophoton, Buffalo, NY 14260 USAUniv Massachusetts, Sch Med, Dept Biochem & Mol Pharmacol, Worcester, MA 01605 USA
Ohulchanskyy, Tymish Y.
Kesseli, Samuel J.
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Univ Massachusetts, Sch Med, Dept Biochem & Mol Pharmacol, Worcester, MA 01605 USAUniv Massachusetts, Sch Med, Dept Biochem & Mol Pharmacol, Worcester, MA 01605 USA
Kesseli, Samuel J.
Buchholz, Steven
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Univ Massachusetts, Sch Med, Dept Biochem & Mol Pharmacol, Worcester, MA 01605 USAUniv Massachusetts, Sch Med, Dept Biochem & Mol Pharmacol, Worcester, MA 01605 USA
Buchholz, Steven
Li, Zhipeng
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Univ N Carolina, Dept Phys & Astron, Chapel Hill, NC 27599 USAUniv Massachusetts, Sch Med, Dept Biochem & Mol Pharmacol, Worcester, MA 01605 USA
Li, Zhipeng
Prasad, Paras N.
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SUNY Buffalo, Dept Chem, Inst Lasers Photon & Biophoton, Buffalo, NY 14260 USA
Korea Univ, Dept Chem, Seoul 136701, South KoreaUniv Massachusetts, Sch Med, Dept Biochem & Mol Pharmacol, Worcester, MA 01605 USA
Prasad, Paras N.
Han, Gang
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Univ Massachusetts, Sch Med, Dept Biochem & Mol Pharmacol, Worcester, MA 01605 USAUniv Massachusetts, Sch Med, Dept Biochem & Mol Pharmacol, Worcester, MA 01605 USA