Synthesis and crystal structure of a novel copper (II) complex with acetylenedicarboxylate and 2, 2′-bipyridine

被引：0
|
作者：
Li, MX [1 ]
Shao, M
Dai, H
An, BL
Lu, WC
Zhu, Y
Du, CX
机构：
[1] Shanghai Univ, Dept Chem, Shanghai 200444, Peoples R China
[2] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China
来源：
CHINESE CHEMICAL LETTERS | 2005年 / 16卷 / 10期
关键词：
copper complex; crystal structure; coordination polymer; acetylenedicarboxylate acid;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound [Cu (ADC) (2, 2'-bipy)](n) (ADC = C-2 (COO)(2)(2-)) was prepared and characterized by elemental analysis, IR spectroscopy, X-ray analysis, respectively. The analysis of the crystal structure reveals that the copper atom is five-coordinated with two nitrogen atoms of 2, 2'-bipy and three oxygen atoms of different acetylenedicarboxylate dianions. ADC as bridging ligands link the Cu (II) ions, forming coordination polymer structure.
引用
收藏
页码：1405 / 1408
页数：4
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