Measurement and correlation of the isobaric vapor-liquid equilibrium for mixtures of alcohol plus ketone systems at atmospheric pressure

被引：11

作者：

Do Seo, Myoung ^{[1
]}

Kim, Young Jo ^{[1
]}

Lim, Jong Sung ^{[2
]}

Kang, Jeong Won ^{[1
]}

机构：

[1] Korea Univ, Dept Chem & Biol Engn, Seoul 136713, South Korea

[2] Sogang Univ, Dept Chem & Biomol Engn, Seoul 121742, South Korea

来源：

KOREAN JOURNAL OF CHEMICAL ENGINEERING | 2012年 / 29卷 / 01期

关键词：

Alcohol; Ketone; Vapor-liquid Equilibrium; Hydrogen Bonding; LATTICE-FLUID EQUATION; PHASE-EQUILIBRIA; 101.3; KPA; BINARY; ETHANOL; ACETONE; STATE; WATER;

D O I：

10.1007/s11814-011-0147-9

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Vapor-liquid equilibrium (VLE) for binary mixtures composed of ethanol+methyl isobutyl ketone, 1-butanol+methyl ethyl ketone, and 1-butanol+methyl propyl ketone systems was measured using a circulation type equilibrium apparatus at atmospheric pressure. The measured data and literature data for alcohol and ketone systems have been correlated by the UNIversal Quasi-Chemical (UNIQUAC) model with two binary interaction parameters and the non-random lattice fluid equation of state with hydrogen bonding equation of state (NLF-HB EoS) using a single binary interaction parameter. For the NLF-HB EoS calculations, the numbers of proton acceptor for ketones were adjusted between 0 and 1. The calculation results with the NLF-HB EoS are better than those with the UNIQUAC model.

引用

页码：103 / 110

页数：8

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