Intermolecular vibration-vibration energy transfer in solution: Hydrogen fluoride in water

被引：20
|
作者：
Laage, D
Demirdjian, H
Hynes, JT
机构：
[1] Ecole Normale Super, PASTEUR, Dept Chim, UMR 8640, F-75231 Paris, France
[2] Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA
来源：
CHEMICAL PHYSICS LETTERS | 2005年 / 405卷 / 4-6期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1016/j.cplett.2005.02.079
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
An explicit formulation for intermolecular vibration-vibration (VV) energy transfer is applied, to the hydrogen fluoride (HF) molecule and the symmetric, antisymmetric and bend overtone vibrations of its hydrogen-boned neighboring water molecule in aqueous solution. The results are analyzed in terms of coupling factor strength and resonance issues. The validity of the point dipole approximation is also investigated. (c) 2005 Elsevier B.V. All rights reserved.
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页码：453 / 458
页数：6
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