Rhodium-catalyzed silylative coupling of olefins with vinylsilanes

被引：24

作者：

Marciniec, B ^{[1
]}

Walczuk-Gusciora, E ^{[1
]}

Pietraszuk, C ^{[1
]}

机构：

[1] Adam Mickiewicz Univ, Fac Chem, Dept Organometall, PL-60780 Poznan, Poland

来源：

CATALYSIS LETTERS | 1998年 / 55卷 / 02期

关键词：

rhodium-complex catalysis; silylative coupling of olefins; vinylsilane;

D O I：

10.1023/A:1019006206468

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

RhH(CO)(PPh3)(3) appeared to be a very effective catalyst for disproportionation of vinylsilanes and their co-disproportionation with styrene and 1-decene. The insertion of vinylsilane (or bis(silyl)ethene) into the Rh-H bond followed by beta-silyl transfer to form a Rh-Si bond and elimination of ethylene (or vinylsilane), in combination with a MS study of the product of the reaction of styrene-d(8) with vinylsilane and well-known insertion of alkene into the Rh-Si bond accounts for a non-metallacarbene mechanism of a new rhodium-catalyzed silylation of olefins with vinylsilanes.

引用

页码：125 / 127

页数：3

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