A membraneless air-breathing hydrogen biofuel cell based on direct wiring of thermostable enzymes on carbon nanotube electrodes

被引:67
|
作者
Lalaoui, Noemie [1 ,2 ]
de Poulpiquet, Anne [3 ]
Haddad, Raoudha [1 ,2 ]
Le Goff, Alan [1 ,2 ]
Holzinger, Michael [1 ,2 ]
Gounel, Sebastien [4 ,5 ]
Mermoux, Michel [6 ,7 ]
Infossi, Pascale [3 ]
Mano, Nicolas [4 ,5 ]
Lojou, Elisabeth [3 ]
Cosnier, Serge [1 ,2 ]
机构
[1] Univ Grenoble Alpes, DCM UMR 5250, F-38000 Grenoble, France
[2] CNRS, DCM UMR 5250, F-38000 Grenoble, France
[3] BIP, BIP, CNRS AMU, F-13009 Marseille, France
[4] CNRS, Ctr Rech Paul Pascal, UPR 8641, F-33600 Pessac, France
[5] Univ Bordeaux, CRPP, UPR 8641, F-33600 Pessac, France
[6] Univ Grenoble Alpes, LEPMI UMR 5279, F-38000 Grenoble, France
[7] CNRS, LEPMI UMR 5279, F-38000 Grenoble, France
关键词
GAS-DIFFUSION; FUEL-CELLS; BOUND HYDROGENASE; OXYGEN-TOLERANT; BIOANODE; POWER; BIOCATHODE; REDUCTION; OXIDASES; DEVICES;
D O I
10.1039/c5cc02166a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A biocathode was designed by the modification of a carbon nanotube (CNT) gas-diffusion electrode with bilirubin oxidase from Bacillus pumilus achieving high current densities up to 3 mA cm(-2) for the reduction of O-2 from air. A membraneless air-breathing hydrogen biofuel cell was designed by combination of this cathode with a functionalized CNT-based hydrogenase anode.
引用
收藏
页码:7447 / 7450
页数:4
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