trans-Bis[2-(piperazin-1-yl)ethanamine]bis(saccharinato)cobalt(II)

被引：2

作者：

Yilmaz, Veysel T. ^{[1
]}

Guney, Serkan ^{[2
]}

Kazak, Canan ^{[3
]}

机构：

[1] Univ Uludag, Fac Arts & Sci, Dept Chem, TR-16059 Bursa, Turkey

[2] Ondokuz Mayis Univ, Fac Arts & Sci, Dept Chem, TR-55019 Kurupelit, Samsun, Turkey

[3] Ondokuz Mayis Univ, Fac Arts & Sci, Dept Phys, TR-55019 Kurupelit, Samsun, Turkey

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷

关键词：

D O I：

10.1107/S1600536807062745

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the centrosymmetric title complex, [Co(C7H4NO3S)(2)(C6H15N3)(2)], the Co-II ion is coordinated by two saccharinate (sac) anions and two neutral 2-piperazin-1-ylethanamine (ppzea) ligands, showing a distorted octahedral coordination. Sac is O-bonded via the carbonyl group, while ppzea acts as an N,N'-bidentate chelating ligand. The molecules are connected by N-H center dot center dot center dot N and N-H center dot center dot center dot O hydrogen bonds, forming a linear chain running parallel to the crystallographic a axis. The compound is isostructural with the reported Ni, Zn, and Cd analogues.

引用

页码：M59 / U601

页数：11

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