Catalytic asymmetric borane reduction of prochiral ketones by the use of diazaborolidine catalysts prepared from chiral β-diamines

被引：34
|
作者：
Sato, S [1 ]
Watanabe, H [1 ]
Asami, M [1 ]
机构：
[1] Yokohama Natl Univ, Fac Engn, Dept Chem & Biotechnol, Hodogaya Ku, Yokohama, Kanagawa 2408501, Japan
来源：
TETRAHEDRON-ASYMMETRY | 2000年 / 11卷 / 21期
关键词：
D O I：
10.1016/S0957-4166(00)00414-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The catalytic asymmetric borane reduction of prochiral ketones was examined in the presence of chiral diazaborolidine catalysts prepared in situ from chiral P-diamines and borane. Chiral secondary alcohols were obtained with modest to high enantiomeric excesses (up to 92% ee) using (S)-2-[(4-trifluoromethyl)anilinomethyl]indoline 2f. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：4329 / 4340
页数：12
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