Three-Component Reaction of Isocyanides and 2-Formylbenzoic Acid with Dibenzylamine Catalyzed by Silica Nanoparticles under Solvent-Free Conditions

被引：72
|
作者：
Ramazani, Ali [1 ]
Mahyari, Amir [1 ]
机构：
[1] Zanjan Univ, Dept Chem, Zanjan, Iran
来源：
HELVETICA CHIMICA ACTA | 2010年 / 93卷 / 11期
基金：
美国国家科学基金会;
关键词：
STABILIZED PHOSPHORUS YLIDES; ELECTRON-POOR ALKENES; ONE-STEP SYNTHESIS; ONE-POT SYNTHESIS; ACETYLENIC ESTERS; STEREOSELECTIVE-SYNTHESIS; GEL POWDER; DERIVATIVES; CONVERSION; (N-ISOCYANIMINO)TRIPHENYLPHOSPHORANE;
D O I：
10.1002/hlca.201000124
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reaction of an isocyanide with an iminium ion intermediate, formed by reaction between 2-formylbenzoic acid and dibenzylamine in the presence of silica nanoparticles NP, ca 42 nm) proceeds smoothly at room temperature to afford isocoumarin (=1H-2 benzopyran-1-one) derivatives in high yields (Scheme I and Table I)
引用
收藏
页码：2203 / 2209
页数：7
相关论文
共 50 条
  • [41] An Efficient Tetrabutylammonium Fluoride (TBAF)-Catalyzed Three-Component Synthesis of 3-Substituted Indole Derivatives under Solvent-Free Conditions
    Singh, Neetu
    Allam, Bharat Kumar
    Raghuvanshi, Dushyant Singh
    Singh, Krishna Nand
    ADVANCED SYNTHESIS & CATALYSIS, 2013, 355 (09) : 1840 - 1848
  • [42] Ytterbium(III) perfluorooctanoate catalyzed one-pot, three-component synthesis of fully substituted pyrazoles under solvent-free conditions
    Shen, Li
    Cao, Song
    Liu, Nianjin
    Wu, Jingjing
    Zhu, Longjie
    Qian, Xuhong
    SYNLETT, 2008, (09) : 1341 - 1344
  • [43] One-pot and three-component synthesis of substituted pyrimidines catalysed by boron sulfuric acid under solvent-free conditions
    Soheilizad, Mehdi
    Adib, Mehdi
    Sajjadifar, Sami
    JOURNAL OF CHEMICAL RESEARCH, 2014, (09) : 524 - 527
  • [44] Copper chloride-catalyzed efficient three-component one-pot synthesis of carbamatoalkyl naphthols under solvent-free conditions
    Song, Zhiguo
    Liu, Lianli
    Sun, Xiaohu
    Cui, Yan
    INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 2014, 53 (06): : 740 - 745
  • [45] Nickel-Catalyzed Solvent-Free Three-Component Coupling of Aldehyde, Alkyne and Amine
    Namitharan, Kayambu
    Pitchumani, Kasi
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2010, 2010 (03) : 411 - 415
  • [46] Mannich reaction catalyzed by a novel catalyst under solvent-free conditions
    Yue, Cai Bo
    Yi, Ting Feng
    Zhu, Chuan Bing
    Liu, Gang
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2009, 15 (05) : 653 - 656
  • [47] Ionic liquids catalyzed Biginelli reaction under solvent-free conditions
    Peng, JJ
    Deng, YQ
    TETRAHEDRON LETTERS, 2001, 42 (34) : 5917 - 5919
  • [48] Novel Three-Component Annulation for the Synthesis of 2,4,6-Triarylpyrimidines under Solvent-Free and Catalyst-Free Conditions
    Ding, Yuxin
    Ma, Yongmin
    Chen, Jing
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2020, 40 (12) : 4357 - 4363
  • [49] An Efficient and Facile Synthesis of Pyrimidine and Quinazoline Derivatives via One-Pot Three-Component Reaction under Solvent-Free Conditions
    Rong, Liangce
    Han, Hongxia
    Wang, Haiying
    Jiang, Hong
    Tu, Shuajiang
    Shi, Daqing
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 2009, 46 (02) : 152 - 157
  • [50] Efficient and Mild Synthesis of Novel Schiff Bases Via One-Pot, Three-Component Reaction Under Solvent-Free Conditions
    Naeimi, Hossein
    Rabiei, Khadijeh
    Salimi, Fariba
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2009, 184 (09) : 2351 - 2357
12345