On the geometric phase effect on tetra-atomic reactions:: the OH+H2→H2O+H reaction

被引：5

作者：

Billing, GD ^{[1
]}

Kuppermann, A

机构：

[1] Univ Copenhagen, HC Orsted Inst, Dept Chem, DK-2200 Copenhagen O, Denmark

[2] CALTECH, Arthur Amos Noyes Lab Chem Phys, Pasadena, CA 91125 USA

来源：

CHEMICAL PHYSICS LETTERS | 1998年 / 294卷 / 1-3期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0009-2614(98)00841-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The geometric phase effect on chemical reactions is investigated for a tetra-atomic reaction using classical mechanics and recently developed row-orthonormal hyperspherical coordinates. The quantum vector potential responsible for the proper handling of the phase of the nuclear wavefunction is incorporated in the classical trajectory equations. This provides a simple estimate of the importance of the geometric phase for reaction cross-sections. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：26 / 30

页数：5

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