Structural investigation of fluorophosphate glasses by 19F, 31P MAS-NMR and IR spectroscopy

被引：21
|
作者：
Djouama, T. [1 ]
Poulain, M. [2 ]
Bureau, B. [2 ]
Lebullenger, R. [2 ]
机构：
[1] USTHB Bab Ezzouar, Lab Elect Quant, Algiers 16111, Algeria
[2] Univ Rennes 1, Sci Chim, F-35042 Rennes, France
来源：
JOURNAL OF NON-CRYSTALLINE SOLIDS | 2015年 / 414卷
关键词：
Fluorophosphate; Glass; Vibrational spectroscopy; NMR; FLUORIDE GLASSES; SPECTRA; PHOSPHATES; ABSORPTION;
D O I：
10.1016/j.jnoncrysol.2015.01.017
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
A series of glass samples of composition [(x)MnF2-(x-80)NaPO3-(20)ZnF2] where x = 0, 10, 20, 30 and 40, has been prepared. IR and NMR spectroscopy have been performed, especially F-19 MAS and P-31 MAS NMR. On the basis of these measurements, glass structure may be described as a hybrid network of ZnF6 and MnF6 octahedra sharing corners and edges and also connected to tetrahedral fluorophosphate groups (PX)(4) where X = O- or F-. Sodium cations fill vacancies of this network. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：16 / 20
页数：5
相关论文
共 50 条
  • [21] 31P and 19F NMR spin trapping of short-lived intermediates
    Khramtsov, VV
    Bagryanskaya, EG
    Potapenko, DI
    Bobko, AA
    Reznikov, VA
    Kolosova, NG
    Clanton, TL
    BIOPHYSICAL JOURNAL, 2004, 86 (01) : 191A - 191A
  • [22] Crystal structure, (31P, 13C) MAS-NMR, IR spectroscopy and thermal investigations of 2,6-dimethylanilinium dihydrogenmonophosphate monohydrate
    Khemiri, H.
    Ben Nasr, C.
    Rzaigui, M.
    Brahim, K.
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2007, 182 (10) : 2269 - 2282
  • [23] 31P MAS-NMR studies of phosphate salts formation on calcium-containing oxide glasses in a simulated body fluid
    Hayakawa, Satoshi
    Tsuru, Kanji
    Iida, Hirohisa
    Ohtsuki, Chikara
    Osaka, Akiyoshi
    1996, Ceramic Soc of Japan, Shinjuku-ku, Tokyo, Japan (104):
  • [24] 31P MAS-NMR studies of CaO-P2O5 glass ceramics
    Dias, AG
    Lopes, MA
    Tsuru, K
    Hayakawa, S
    Santos, JD
    Osaka, A
    BIOCERAMICS 18, PTS 1 AND 2, 2006, 309-311 : 301 - 304
  • [25] Structural features of acidic fluorophosphatozirconates (hafnates) from the 19F, 31P, 1H NMR data
    Slobodyuk, A. B.
    Kavun, V. Ya.
    Godneva, M. M.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 57 (02) : 338 - 344
  • [26] 31P MAS-NMR of human erythrocytes:: Independence of cell volume from angular velocity
    Kuchel, PW
    Bubb, WA
    Ramadan, S
    Chapman, BE
    Philp, DJ
    Coen, M
    Gready, JE
    Harvey, PJ
    McLean, AJ
    Hook, J
    MAGNETIC RESONANCE IN MEDICINE, 2004, 52 (03) : 663 - 668
  • [27] Structural features of acidic fluorophosphatozirconates (hafnates) from the 19F, 31P, 1H NMR data
    A. B. Slobodyuk
    V. Ya. Kavun
    M. M. Godneva
    Journal of Structural Chemistry, 2016, 57 : 338 - 344
  • [28] A solid acidity scale based on the 31P MAS-NMR shift of chemisorbed triethylphosphine oxide
    Osegovic, JP
    Drago, RS
    JOURNAL OF CATALYSIS, 1999, 182 (01) : 1 - 4
  • [29] Hydrothermal synthesis of nanoporous metalofluorophosphates.: 1.: Precursor solutions of titanium fluoride and fluorophosphate in water, a 19F and 31P NMR study
    Serre, C
    Corbiére, T
    Lorentz, C
    Taulelle, F
    Férey, G
    CHEMISTRY OF MATERIALS, 2002, 14 (12) : 4939 - 4947
  • [30] The determination of phosphorus containing compounds in dental casting investment products by 31P solid-state MAS-NMR spectroscopy
    Scrimgour, Sheelagh N.
    Chudek, John A.
    Lloyd, Charles H.
    DENTAL MATERIALS, 2007, 23 (04) : 415 - 424
12345