Characterization and molecular structure of bis(isopropyl xanthate) bis(1,10-phenanthroline) nickel(II):: [Ni(phen)2(CH3)2CHOCSS](CH3)2CHOCSS

被引：7
|
作者：
Xu, KJ [1 ]
Ding, WP
Meng, W
Hu, F
机构：
[1] China Pharmaceut Univ, Phys Chem Lab, Nanjing 210009, Peoples R China
[2] Nanjing Univ, Phys Chem Lab, Nanjing 210008, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2003年 / 56卷 / 09期
关键词：
nickel complex; 1,10-phenanthroline ligands; xanthate;
D O I：
10.1080/0095897031000110673
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal and molecular structure of the title compound, [Ni(phen)(2)(CH3)(2)CHOCSS](CH3)(2)CHOCSS has been determined by X-ray diffraction. The brown crystal is triclinic of space group P1, with parameters a=11.790(2), b=12.410(3), c=12.680(3)Angstrom, alpha=92.49(3), beta=96.54(3), gamma=117.43(3), and Z=2. The compound contains a six-coordinate cation and an isopropyl xanthate anion (CH3)(2)CHOCSS-, the central Ni atom is chelated by four nitrogen atoms of two phenanthroline ligands and two sulfur atoms of an isopropyl xanthate ligand. The TG data indicate that it decomposed completely at 734degreesC.
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收藏
页码：797 / 801
页数：5
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