Synthesis, Characterization, and Photophysical Properties of Triptycene-Based Chiral Organoboranes

被引：5

作者：

Zhang, Songhe ^{[1
]}

Chen, Jin-Fa ^{[1
]}

Hu, Guofei ^{[1
]}

Zhang, Niu ^{[2
]}

Wang, Nan ^{[1
]}

Yin, Xiaodong ^{[1
]}

Chen, Pangkuan ^{[1
]}

机构：

[1] Beijing Inst Technol China, Sch Chem & Chem Engn, Key Lab Cluster Sci,Minist Educ, Beijing Key Lab Photoelect Electrophoton Convers, Beijing 102488, Peoples R China

[2] Beijing Inst Technol, Anal & Testing Ctr, Beijing 102488, Peoples R China

来源：

ORGANOMETALLICS | 2022年 / 41卷 / 02期

基金：

中国国家自然科学基金;

关键词：

INTRAMOLECULAR CHARGE-TRANSFER; ORGANIC-DYES; FLUORESCENCE; EFFICIENT; ELECTROLUMINESCENCE; INDUCTION; MOLECULES; POLYMER;

D O I：

10.1021/acs.organomet.1c00447

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Chiral luminescent triptycenes (HC-BN and HC-BB) functionalized with electron-donating carbazole and electron-accepting triarylborane were synthesized by classical Buchwald-coupling and Suzuki-coupling reactions. The compound bearing both carbazole and triarylborane, HC-BN, exhibits significant thermochromic shift of the emission because of the intramolecular including circular dichroism (CD) and circularly polarized luminescence (CPL), are further studied because of the inherent chirality of triptycene derivatives. This work may contribute to the development of new chiral luminescent materials based on the rigid, homoconjugated, and structurally unusual three-dimensional triptycene scaffolds.

引用

页码：99 / 104

页数：6

共 50 条

[31] A general asymmetric synthesis based on chiral organoboranes.
Brown, HC
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 215 : U10 - U10
[32] Synthesis of highly gas-selective triptycene-based polymers of intrinsic microporosity (TPIMs)
Ghanem, Bader
Swaidan, Raja
Litwiller, Eric
Pinnau, Ingo
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 249
[33] Triptycene-based microporous polyimides: Synthesis and their high selectivity for CO2 capture
Zhang, Chun
Zhai, Tian-Long
Wang, Jing-Jing
Wang, Zhen
Liu, Jun-Min
Tan, Bien
Yang, Xiang-Liang
Xu, Hui-Bi
POLYMER, 2014, 55 (16) : 3642 - 3647
[34] Repetitive Rolling of Triptycene-Based Molecules on Cu Surfaces
Konuk, Mine
Madran, Melihat
Uysal, Mehmet Tuna
Beser, Deniz
Ozen, Alimet Sema
Akdeniz, Zehra
Durukanoglu, Sondan
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2024, 146 (39) : 27014 - 27021
[35] Investigation of triptycene-based surface-mounted rotors
Hou, SM
Sagara, T
Xu, DC
Kelly, TR
Ganz, E
NANOTECHNOLOGY, 2003, 14 (05) : 566 - 570
[36] Triptycene-Based Microporous Polymer Incorporating Thioamide Functionality: Preparation and Gas Storage Properties
Liu, Lei
Xia, Yijie
Zhang, Jie
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2015, 53 (19) : 2193 - 2197
[37] Synthesis of rigid chiral C3-symmetric triptycene-based ligands and their application in enantioselective Cu(I)-catalyzed aziridination of chalcones
Kisets, Ilya
Gelman, Dmitri
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2021, 941
[38] Development of triptycene-based nucleic acid junction binders
Barros, Stephanie
Chenoweth, David
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 250
[39] Synthesis of soluble and thermally stable triptycene-based poly(amide-imide)s
Sheng-Huei Hsiao
Wenjeng Guo
Teh-Hua Tsai
Yu-Ting Chiu
Journal of Polymer Research, 2014, 21
[40] Synthesis, Structure, and Complexation Properties of a C3-Symmetrical Triptycene-Based Anion Receptor: Selectivity for Dihydrogen Phosphate
Granda, Jaroslaw M.
Grabowski, Jakub
Jurczak, Janusz
ORGANIC LETTERS, 2015, 17 (23) : 5882 - 5885

← 1 2 3 4 5 →