A binuclear manganese(II) complex:: di-μ-acetato-κ4O:O′- bis[bis(1,10-phenanthroline-κ2N,N′)manganese(II)] bis(perchlorate)

被引：1
|
作者：
Niu, XL
Dou, JM
Hu, CW [1 ]
Li, DC
Wang, DQ
机构：
[1] Beijing Inst Technol, Inst Chem Phys, Beijing 100081, Peoples R China
[2] Liaocheng Univ, Sch Chem & Chem Engn, Liaocheng 252059, Peoples R China
[3] Beijing Inst Technol, Dept Chem, Beijing 100081, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2005年 / 61卷
关键词：
D O I：
10.1107/S1600536805027479
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title binuclear manganese(II) complex, [Mn-2(C2H3O2)(2-) C12H8N2)(4)](ClO4)(2), has been synthesized by the reaction of manganese(II) acetate and tetra-n- butylammonium manganate(VII) with 1,10-phenanthroline in a mixed solvent of acetic acid, ethanol and pyridine. In the centrosymmetric cation, the two Mn-II atoms are linked to each other by the four O atoms of two acetate ions. Each Mn-II atom adopts a six-coordinate geometry and the six coordinating atoms form a distorted octahedron.
引用
收藏
页码：M1909 / M1911
页数：3
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