Separation of Ru(III), Rh(III) and Pd(II) from nitric acid solutions using ion-exchange resins bearing carboxylic betaine

被引：9

作者：

Suzuki, Tomoya ^{[1
,2
]}

Morita, Keisuke ^{[1
]}

Sasaki, Yuji ^{[1
]}

Matsumura, Tatsuro ^{[1
]}

机构：

[1] Japan Atom Energy Agcy, Tokai, Ibaraki, Japan

[2] Natl Inst Adv Ind Sci & Technol, 16-1 Onogawa, Tsukuba, Ibaraki 3058569, Japan

来源：

SEPARATION SCIENCE AND TECHNOLOGY | 2016年 / 51卷 / 17期

关键词：

Ruthenium; rhodium; palladium; adsorption; high-level liquid waste; LIQUID-LIQUID-EXTRACTION; HNO3; AQUEOUS-SOLUTION; PLATINUM-GROUP METALS; SOLVENT-EXTRACTION; RADIOACTIVE-WASTE; RARE-EARTHS; COMPLEXES; BIS(TRIFLUOROMETHYLSULFONYL)IMIDE; BEHAVIOR; LIGANDS;

D O I：

10.1080/01496395.2016.1216568

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

To understand the adsorption properties of a styrene-divinylbenzene copolymer functionalized with N,N,N-trimethylglycine, AMP03, the adsorption behaviours for platinoid ions (Ru(III), Rh(III) and Pd(II)) were examined. Furthermore, we performed adsorption experiments using sample solutions by adding triethylamine, thiourea and N,N,N-trimethylglycine. Based on the adsorption data obtained in this study, we performed chromatographic experiments. The results indicated that all platinoid ions in the feed solution completely adsorbed on AMP03, and almost 80% of the adsorbed platinoid ions were recovered. These results show that AMP03 has the potential to recover Ru(III), Rh(III) and Pd(II) from high-level liquid waste.

引用

页码：2815 / 2822

页数：8

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