Binuclear silver(I) complexes with polydentate phosphine ligands 2-(diphenylphosphino)-6-[3-(2′-pyridyl)pyrazol-1-yl]pyridine and 2-(diphenylphosphino)-6-(pyrazol-1-yl)pyridine

被引：24
|
作者：
Kuang, SM
Zhang, ZZ [1 ]
Wang, QG
Mak, TCW
机构：
[1] Nankai Univ, Elementoorgan Chem Lab, Tianjin 300071, Peoples R China
[2] Chinese Univ Hong Kong, Dept Chem, Shatin, New Territories, Peoples R China
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 17期
关键词：
D O I：
10.1039/a803704c
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The new polydentate, pyridine-based phosphine ligand 2-(diphenylphosphino)-6-[3-(2'-pyridyl)-1-yl]-pyridine (L-2) has been synthesized. The reaction of L-2 With [Ag(MeCN)(4)][ClO4] resulted in the formation of the binuclear silver(I) complex [Ag-2(mu-L-2)(2)(ClO4)(2)], which is stabilized by significant pi-pi stacking interactions between its inter-ligand pyridyl fragments. In contrast, the reaction of 2-(diphenyiphosphino)-6-(pyrazol-1-yl)pyridine (L-1) with [Ag(MeCN)(4)][ClO4] gave the binuclear complex [Ag-2(mu-L-1)(2)(MeCN)(2)][ClO4](2), which exhibits a weak metal-metal interaction.
引用
收藏
页码：2927 / 2929
页数：3
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