Asymmetric Hydroformylation

被引：42

作者：

Claver, Carmen ^{[1
]}

Dieguez, Montserrat ^{[1
]}

Pamies, Oscar ^{[1
]}

Castillon, Sergio ^{[2
]}

机构：

[1] Univ Rovira & Virgili, Dept Phys Chem & Inorgan Chem, Tarragona 43007, Spain

[2] Univ Rovira & Virgili, Dept Analyt Chem & Organ Chem, Tarragona 43007, Spain

来源：

CATALYTIC CARBONYLATION REACTIONS | 2006年 / 18卷

关键词：

Aldehydes; Catalysis; Enantioselectivity; Hydroformylation; Intermediates; Rhodium;

D O I：

10.1007/3418_016

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This chapter presents the latest achievements reported in the asymmetric hydroformylation of olefins. It focuses on rhodium systems containing diphosphites and phosphine-phosphite ligands, because of their significance in the subject. Particular attention is paid to the mechanistic aspects and the characterization of intermediates in the hydroformylation of vinyl arenes because these are the most important breakthroughs in the area. The chapter also presents the application of this catalytic reaction to vinyl acetate, dihydrofurans and unsaturated nitriles because of its industrial relevance.

引用

页码：35 / 64

页数：30

共 50 条

[21] Iterative Asymmetric Hydroformylation/Wittig Olefination Sequence
Wong, Gene W.
Landis, Clark R.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (05) : 1564 - 1567
[22] Asymmetric hydroformylation of vinylarenes with rhodium diphosphite catalyst
Uriz, P
Fernández, E
Ruiz, N
Claver, C
INORGANIC CHEMISTRY COMMUNICATIONS, 2000, 3 (10) : 515 - 519
[23] Chiral (diphosphonite)platinum complexes in asymmetric hydroformylation
van Duren, Ruben
Cornelissen, Leandra L. J. M.
van der Vlugt, Jarl Ivar
Huijbers, Jeroen P. L.
Mills, Allison M.
Spek, Anthony L.
Muller, Christian
Vogt, Dieter
HELVETICA CHIMICA ACTA, 2006, 89 (08) : 1547 - 1558
[24] Application of an enantiopure scaffolding ligand to asymmetric hydroformylation
Joe, Candice L.
Tan, Kian L.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
[25] ASYMMETRIC HYDROFORMYLATION OF OLEFINIC HYDROCARBONS BY PLATINUM CATALYSTS
CONSIGLIO, G
ARBER, W
PINO, P
CHIMICA & L INDUSTRIA, 1978, 60 (05): : 396 - 400
[26] Progress in chiral ligands for asymmetric catalytic hydroformylation
Ren, YL
Zhao, WC
Lu, SJ
PROGRESS IN CHEMISTRY, 2004, 16 (02) : 266 - 272
[27] HIGHLY SELECTIVE, RHODIUM CATALYZED ASYMMETRIC HYDROFORMYLATION
BABIN, JE
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 205 : 248 - INOR
[28] ASYMMETRIC HYDROFORMYLATION OF OLEFINS IN PRESENCE OF RHODIUM AND COBALT
PINO, P
CONSIGLI.G
BOTTEGHI, C
SALOMON, C
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1973, (AUG26): : 3 - 3
[29] New diphosphite ligands for enantioselective asymmetric hydroformylation
Zou, Yaping
Yan, Yongjun
Zhang, Xumu
TETRAHEDRON LETTERS, 2007, 48 (27) : 4781 - 4784
[30] Asymmetric hydroformylation of styrene in supercritical carbon dioxide
Kleman, AM
Abraham, MA
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (04) : 1324 - 1330

← 1 2 3 4 5 →